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Absolute ion hydration enthalpies and the role of volume within hydration thermodynamics
JournalArticle (Originalarbeit in einer wissenschaftlichen Zeitschrift)
 
ID 3812280
Author(s) Housecroft, Catherine E.; Jenkins, H. Donald Brooke
Author(s) at UniBasel Housecroft, Catherine
Year 2017
Title Absolute ion hydration enthalpies and the role of volume within hydration thermodynamics
Journal RSC Advances
Volume 7
Number 45
Pages / Article-Number 27881-27894
Keywords Thermodynamics; enthalpies of hydration; Volume-based thermodynamics
Abstract This paper reports that various thermodynamic properties in aqueous media for certain individual ions and for compounds are linear functions of the inverse cube root of the solid respective ionic and compound solid state volumes, V m –1/3 . This is similar to the situation which has been fully exploited in solid state thermodynamics and out of which Volume–Based Thermodynamics, VBT evolved. A short resume of these various VBT applications is provided for the general reader and an improved lattice potential energy equation emerges using the state of the art data presented in this paper.
Publisher Royal Society of Chemistry
ISSN/ISBN 2046-2069
edoc-URL http://edoc.unibas.ch/55324/
Full Text on edoc Available
Digital Object Identifier DOI 10.1039/c6ra25804b
ISI-Number WOS:000402999300007
Document type (ISI) Article
 
   

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