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Determining the enantioselectivity of chiral catalysts by mass spectrometric screening of their racemic forms
JournalArticle (Originalarbeit in einer wissenschaftlichen Zeitschrift)
 
ID 973328
Author(s) Ebner, Christian; Müller, Constanze A.; Markert, Christian; Pfaltz, Andreas
Author(s) at UniBasel Pfaltz, Andreas
Ebner, Christian
Year 2011
Title Determining the enantioselectivity of chiral catalysts by mass spectrometric screening of their racemic forms
Journal Journal of the American Chemical Society
Volume 133
Number 13
Pages / Article-Number 4710-3
Abstract The enantioselectivity of a chiral catalyst can be determined from its racemic form by mass spectrometric screening of a nonequal mixture of two mass-labeled quasienantiomeric substrates. The presented method opens up new possibilities for evaluating catalyst structures that are not readily available in enantiomerically pure form.
Publisher American Chemical Society
ISSN/ISBN 0002-7863 ; 1520-5126
edoc-URL http://edoc.unibas.ch/dok/A5849079
Full Text on edoc No
Digital Object Identifier DOI 10.1021/ja111700e
PubMed ID http://www.ncbi.nlm.nih.gov/pubmed/21401128
ISI-Number WOS:000289492700014
Document type (ISI) Journal Article
 
   

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