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A Synthetic Entry into the Taiwaniaquinoids Based on a Biogenetic Hypothesis : Total Synthesis of (-)-Taiwaniaquinone H
JournalArticle (Originalarbeit in einer wissenschaftlichen Zeitschrift)
 
ID 462464
Author(s) Jana, C. K.; Scopelliti, R.; Gademann, K.
Author(s) at UniBasel Gademann, Karl
Year 2010
Title A Synthetic Entry into the Taiwaniaquinoids Based on a Biogenetic Hypothesis : Total Synthesis of (-)-Taiwaniaquinone H
Journal Chemistry - A European Journal
Volume 16
Number 26
Pages / Article-Number 7692-7695
Keywords natural products, protecting-group-free synthesis, rearrangement, terpenes, total synthesis
Abstract

Less carbon: Following a biogenetic proposal, the unusual 6-5-6 carbon skeleton of C19 taiwaniaquinoids was obtained by an intramolecular benzilic acid rearrangement from a C20 precursor. A protecting-group-free total synthesis then allowed for the preparation of (−)-taiwaniaquinone H (see scheme).

Publisher Wiley
ISSN/ISBN 0947-6539 ; 1521-3765
edoc-URL http://edoc.unibas.ch/dok/A5841598
Full Text on edoc Restricted
Digital Object Identifier DOI 10.1002/chem.201001085
PubMed ID http://www.ncbi.nlm.nih.gov/pubmed/20533471
ISI-Number WOS:000280431900005
Document type (ISI) Article
 
   

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19/04/2024