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Photophysics and Photoredox Catalysis of a Homoleptic Rhenium(I) Tris(diisocyanide) Complex
JournalArticle (Originalarbeit in einer wissenschaftlichen Zeitschrift)
 
ID 4480445
Author(s) Larsen, Christopher B.; Wenger, Oliver S.
Author(s) at UniBasel Wenger, Oliver
Larsen, Christopher Bryan
Year 2018
Title Photophysics and Photoredox Catalysis of a Homoleptic Rhenium(I) Tris(diisocyanide) Complex
Journal Inorganic Chemistry
Volume 57
Number 6
Pages / Article-Number 2965-2968
Abstract Herein a homoleptic rhenium(I) complex bearing three chelating diisocyanide ligands and its photophysical properties are communicated. The complex emits weakly from a high-energy triplet metal-to-ligand charge-transfer excited state with an 8 ns lifetime in deaerated CH3CN at 22 °C and is shown to act as an efficient photoredox catalyst comparable to [Ir(ppy)3] (ppy = 2-phenylpyridine) in representative test reactions.
Publisher American Chemical Society
ISSN/ISBN 0020-1669 ; 1520-510X
edoc-URL https://edoc.unibas.ch/64613/
Full Text on edoc Available
Digital Object Identifier DOI 10.1021/acs.inorgchem.7b03258
PubMed ID http://www.ncbi.nlm.nih.gov/pubmed/29509002
Document type (ISI) Journal Article
 
   

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