An evaluation of the relationship between two- and three-dimensional packing in self-organised monolayers and bulk crystals of amphiphilic 2,2 ': 6 ',2 ''-terpyridines
JournalArticle (Originalarbeit in einer wissenschaftlichen Zeitschrift)
 
ID 43296
Author(s) Constable, Edwin C.; Guentherodt, H. -J.; Housecroft, Catherine E.; Merz, Leo; Neuburger, Markus; Schaffner, Silvia; Tao, Yaqiu
Author(s) at UniBasel Constable, Edwin Charles
Year 2006
Title An evaluation of the relationship between two- and three-dimensional packing in self-organised monolayers and bulk crystals of amphiphilic 2,2 ': 6 ',2 ''-terpyridines
Journal New Journal of Chemistry
Volume 30
Number 10
Pages / Article-Number 1470-1479
Abstract 2,2 ': 6 ',2 ''-Terpyridine (tpy) ligands with pendant octadecyloxy, 4-octyloxyphenyl or 4-octadecyloxyphenyl substituents at the 4`-position have been prepared and structurally characterised. Monolayers of the compounds have been prepared on highly oriented pyrolytic graphite (HOPG) and investigated by STM. The monolayer structure corresponds to the bulk crystal structure if the latter contains planar sheets. The tpy ligands are prochiral and form homochiral domains within the monolayer, providing a spectacular visual representation of the symmetry-breaking concomitant with the formation of a monolayer.
Publisher Royal Society of Chemistry
ISSN/ISBN 1144-0546 ; 1369-9261
edoc-URL http://edoc.unibas.ch/39169/
Full Text on edoc No
Digital Object Identifier DOI 10.1039/b608136c
ISI-Number 000241036000014
 
   

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