A one-dimensional copper(II) coordination polymer containing [Fe(pytpy)2]2+ (pytpy = 4′-(4-pyridyl)-2,2′:6′,2″-terpyridine) as an expanded 4,4′-bipyridine ligand : a hydrogen-bonded network penetrated by rod-like polymers
JournalArticle (Originalarbeit in einer wissenschaftlichen Zeitschrift)
 
ID 43274
Author(s) Beves, Jonathon E.; Constable, Edwin C.; Housecroft, Catherine E.; Neuburger, Markus; Schaffner, Silvia
Author(s) at UniBasel Constable, Edwin Charles
Housecroft, Catherine
Neuburger, Markus
Year 2008
Title A one-dimensional copper(II) coordination polymer containing [Fe(pytpy)2]2+ (pytpy = 4′-(4-pyridyl)-2,2′:6′,2″-terpyridine) as an expanded 4,4′-bipyridine ligand : a hydrogen-bonded network penetrated by rod-like polymers
Journal CrystEngComm
Volume 10
Number 3
Pages / Article-Number 344-348
Abstract The one-dimensional coordination polymer [(H2O)(NO3)(2)CuFe(1)(2)(2)(NO3)(4)center dot 2.15MeCN center dot 5.85H(2)O](n) assembles when the pendant pyridine donors in [Fe(1)(2)](2+) (1 = 4`-(4-pyridyl)2,2`: 6`,2 ``-terpyridine) are treated with Cu(NO3)(2)center dot 3H(2)O, exemplifying [Fe(1)(2)](2+) as an expanded 4,4`-bipyridine ligand. In the solid state, the polymer chains are threaded through hydrogen-bonded macrocycles comprising coordinated and non-coordinated water molecules and nitrate ions, the macrocycles being motifs within interconnected sheets in the structure.
Publisher Royal Society of Chemistry
ISSN/ISBN 1466-8033
edoc-URL http://edoc.unibas.ch/dok/A6056006
Full Text on edoc No
Digital Object Identifier DOI 10.1039/b713001e
ISI-Number 000253642200014
Document type (ISI) Article
 
   

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