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Diastereoselective formation of a complex with an atropisomeric 4,4′-biquinazoline ligand: The solid-state structure of cis-bis(4,4′-biquinazoline)dichloridoiridium(III) hexafluoridophosphate
JournalArticle (Originalarbeit in einer wissenschaftlichen Zeitschrift)
Diastereoselective formation of a complex with an atropisomeric 4,4′-biquinazoline ligand: The solid-state structure of cis-bis(4,4′-biquinazoline)dichloridoiridium(III) hexafluoridophosphate
The ligand 4,4`-biquinazoline (biqz) forms complexes in which it adopts either the P or M atropisomeric configuration; the complex cis-[1r(biqz)(2)Cl-2][PF6] center dot MeCN has been structurally characterised and shown to comprise a single enantionteric pair (PM-Delta)(MP-Lambda) of the six possible stereoisomers.
