A new twist to 3,6-bis(2-pyridyl)-1,2,4,5-tetrazine complexes of silver(I)
JournalArticle (Originalarbeit in einer wissenschaftlichen Zeitschrift)
ID 43261
Author(s) Constable, Edwin C.; Housecroft, Catherine E.; Neuburger, Markus; Reymann, Sebastien; Schaffner, Silvia
Author(s) at UniBasel Constable, Edwin Charles
Housecroft, Catherine
Neuburger, Markus
Year 2008
Title A new twist to 3,6-bis(2-pyridyl)-1,2,4,5-tetrazine complexes of silver(I)
Journal CrystEngComm
Volume 10
Number 8
Pages / Article-Number 991-995
Abstract The dinuclear complex [Ag-2(1)(3)](2+) has been isolated as the triflate salt from the reaction of silver(I) triflate with 3,6-bis(2-pyridyl)-1,2,4,5-tetrazine (1) in acetonitrile. The single crystal structure of [Ag-2(1)(3)][CF3SO3](2)center dot MeCN reveals a trigonal prismatic coordination environment for each silver(I) centre. The isolation of [Ag-2(1)(3)][CF3SO3](2)center dot MeCN contrasts with our earlier observation that crystalline [Ag-2(1)(2)][CF3SO3](2) can be isolated from a 1 : 1 reaction of AgCF3SO3. These data are discussed in the context of other published observations of similar systems, and the present results suggest that the reasons governing the assembly of a given structural architecture between Ag+ and 1 are more subtle than simply the choice of anion.
Publisher Royal Society of Chemistry
ISSN/ISBN 1466-8033
edoc-URL http://edoc.unibas.ch/dok/A6055999
Full Text on edoc No
Digital Object Identifier DOI 10.1039/b803006e
ISI-Number 000257875100015
Document type (ISI) Article

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