A new polymorph of 4'-tolyl-2,2':6',2''-terpyridine (ttpy) and the single crystal structures of [Fe(ttpy)2][PF6]2 and [Ru(ttpy)2][PF6]2
JournalArticle (Originalarbeit in einer wissenschaftlichen Zeitschrift)
 
ID 43254
Author(s) Beves, Jonathon E.; Chwalisz, Paulina; Constable, Edwin C.; Housecroft, Catherine E.; Neuburger, Markus; Schaffner, Silvia; Zampese, Jennifer A.
Author(s) at UniBasel Constable, Edwin Charles
Housecroft, Catherine
Neuburger, Markus
Year 2008
Title A new polymorph of 4'-tolyl-2,2':6',2''-terpyridine (ttpy) and the single crystal structures of [Fe(ttpy)2][PF6]2 and [Ru(ttpy)2][PF6]2
Journal Inorganic Chemistry Communications
Volume 11
Number 9
Pages / Article-Number 1009-1011
Keywords 4 '-tolyl-2,2 ': 6 ',2 ''-terpyridine, coordination, polymorph, iron, ruthenium
Abstract Single crystals of a new polymorph of 4`-tolyl-2,2`:6`,2 ``-terpyridine (ttpy) have been grown by evaporation of a hexane-ethyl acetate solution of the ligand; the packing features weak pi-stacking and N-Pyridine...HC interactions between stacks of ttpy molecules. Improved syntheses of [M(ttpy)(2)][PFr](2) (M = Fe, Ru), and the single crystal structures of [Fe(ttpy)(2)][PF6](2)center dot 2.2MeCN and [Ru(ttpy)21[PF6](2)center dot 1.75MeCN center dot 0.2H(2)O are reported.
Publisher Elsevier
ISSN/ISBN 1387-7003
edoc-URL http://edoc.unibas.ch/dok/A6055993
Full Text on edoc No
Digital Object Identifier DOI 10.1016/j.inoche.2008.04.033
ISI-Number 000259763800020
Document type (ISI) Article
 
   

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