4′-Chloro-2,2′:6′,2″-terpyridine (L): ethyl sulfate salts of [H2L]2+ and the single crystal structures of [H2L][EtOSO3]Cl · H2O and [ML2][PF6]2 with M = Fe and Ru
JournalArticle (Originalarbeit in einer wissenschaftlichen Zeitschrift)
 
ID 43253
Author(s) Beves, Jonathon E.; Constable, Edwin C.; Housecroft, Catherine E.; Neuburger, Markus; Schaffner, Silvia; Zampese, Jennifer A.
Author(s) at UniBasel Constable, Edwin Charles
Housecroft, Catherine
Year 2008
Title 4′-Chloro-2,2′:6′,2″-terpyridine (L): ethyl sulfate salts of [H2L]2+ and the single crystal structures of [H2L][EtOSO3]Cl · H2O and [ML2][PF6]2 with M = Fe and Ru
Journal Inorganic Chemistry Communications
Volume 11
Number 9
Pages / Article-Number 1006-1008
Keywords 4 '-chloro-2,2 ': 6 ',2 ''-rerpyridine, heterocyclic, coordination, iron, ruthenium
Abstract The preparation and characterization of [H(2)1][ErOSO3](2) and the crystal structure of [H(2)1][EtOSO3]Cl center dot H2O are reported (1 =4`-chloro-2,2`:6`,2 ``-terpyridine): extensive hydrogen bonding dictates both the conformation of the tpy domain and the crystal packing. An efficient microwave oven synthesis of [Ru(1)(2)][PF6](2) is described; the method has general application for [Ru(tpy)(2)](2+) derivatives. In the solid state, [Ru(1)(2)][PF6](2) and [Fe(1)(2)[[PF6](2) are isostructural and crystallize in the tetragonal P42(1)c space group.
Publisher Elsevier
ISSN/ISBN 1387-7003
edoc-URL http://edoc.unibas.ch/dok/A5248850
Full Text on edoc No
Digital Object Identifier DOI 10.1016/j.inoche.2008.04.026
ISI-Number 000259763800019
Document type (ISI) Article
 
   

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