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4′-Chloro-2,2′:6′,2″-terpyridine (L): ethyl sulfate salts of [H2L]2+ and the single crystal structures of [H2L][EtOSO3]Cl · H2O and [ML2][PF6]2 with M = Fe and Ru
JournalArticle (Originalarbeit in einer wissenschaftlichen Zeitschrift)
ID
43253
Author(s)
Beves, Jonathon E.; Constable, Edwin C.; Housecroft, Catherine E.; Neuburger, Markus; Schaffner, Silvia; Zampese, Jennifer A.
4′-Chloro-2,2′:6′,2″-terpyridine (L): ethyl sulfate salts of [H2L]2+ and the single crystal structures of [H2L][EtOSO3]Cl · H2O and [ML2][PF6]2 with M = Fe and Ru
The preparation and characterization of [H(2)1][ErOSO3](2) and the crystal structure of [H(2)1][EtOSO3]Cl center dot H2O are reported (1 =4`-chloro-2,2`:6`,2 ``-terpyridine): extensive hydrogen bonding dictates both the conformation of the tpy domain and the crystal packing. An efficient microwave oven synthesis of [Ru(1)(2)][PF6](2) is described; the method has general application for [Ru(tpy)(2)](2+) derivatives. In the solid state, [Ru(1)(2)][PF6](2) and [Fe(1)(2)[[PF6](2) are isostructural and crystallize in the tetragonal P42(1)c space group.
