A supramolecularly-caged ionic iridium (III) complex yielding bright and very stable solid-state light-emitting electrochemical cells
JournalArticle (Originalarbeit in einer wissenschaftlichen Zeitschrift)
 
ID 43250
Author(s) Graber, Stefan; Doyle, Kevin; Neuburger, Markus; Housecroft, Catherine E.; Constable, Edwin C.; Costa, Ruben D.; Orti, Enrique; Repetto, Diego; Bolink, Henk J.
Author(s) at UniBasel Constable, Edwin Charles
Neuburger, Markus
Housecroft, Catherine
Year 2008
Title A supramolecularly-caged ionic iridium (III) complex yielding bright and very stable solid-state light-emitting electrochemical cells
Journal Journal of the American Chemical Society
Volume 130
Number 45
Pages / Article-Number 14944-+
Abstract A new iridium(III) complex showing intramolecular interligand pi-stacking has been synthesized and used to improve the stability of single-component, solid-state light-emitting electrochemical cell (LEC) devices. The pi-stacking results in the formation of a very stable supramolecularly caged complex. LECs using this complex show extraordinary stabilities (estimated lifetime of 600 h) and luminance values (average luminance of 230 cd m-2) indicating the path toward stable ionic complexes for use in LECs reaching stabilities required for practical applications.
Publisher American Chemical Society
ISSN/ISBN 0002-7863 ; 1520-5126
edoc-URL http://edoc.unibas.ch/dok/A5251865
Full Text on edoc No
Digital Object Identifier DOI 10.1021/ja805900e
PubMed ID http://www.ncbi.nlm.nih.gov/pubmed/18937473
ISI-Number WOS:000260682300021
Document type (ISI) Article
 
   

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