A double-stranded 1D-coordination polymer assembled using the tetravergent ligand 1,1′-bis(4,2′:6′,4″-terpyridin-4′-yl)ferrocene
JournalArticle (Originalarbeit in einer wissenschaftlichen Zeitschrift)
 
ID 3532237
Author(s) Klein, Y. M.; Prescimone, A.; Constable, E. C.; Housecroft, C. E.
Author(s) at UniBasel Housecroft, Catherine
Constable, Edwin Charles
Klein, Maximilian
Prescimone, Alessandro
Year 2016
Title A double-stranded 1D-coordination polymer assembled using the tetravergent ligand 1,1′-bis(4,2′:6′,4″-terpyridin-4′-yl)ferrocene
Journal Inorganic chemistry communications
Volume 70
Pages / Article-Number 118-120
Abstract

1,1′-Bis(4,2′:6′,4″-terpyridin-4′-yl)ferrocene (1) reacts with ZnCl2 to yield a double-stranded 1D-coordination polymer [{Zn2(1)Cl4}∙3CHCl3]n. The 1,1′-functionalized ferrocene core adopts a cisoid-conformation, giving rise to a folded conformation for 1 and a double-stranded 1D-polymer chain. This contrasts with previously reported multi-stranded chains supported by 4,2′:6′,4″-terpyridine ligands in which the multiple-nature of the chain arises from multinuclear metal nodes.

Publisher Elsevier
ISSN/ISBN 1387-7003
edoc-URL http://edoc.unibas.ch/43296/
Full Text on edoc Restricted
Digital Object Identifier DOI 10.1016/j.inoche.2016.05.027
ISI-Number WOS:000380865300028
Document type (ISI) Article
 
   

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