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Cethrene: A Helically Chiral Biradicaloid Isomer of Heptazethrene
Journal
Angewandte Chemie International Edition
Volume
55
Number
3
Pages / Article-Number
1183-6
Abstract
We report the synthesis and properties of "cethrene", the only helically chiral isomer of heptazethrene with a biradicaloid singlet ground state. Cethrene gives a well-resolved EPR spectrum at room temperature and its structure was confirmed by 2D NMR and absorption spectroscopies. Our experiments and calculations show that the helical twist affects its electronic properties and decreases the singlet-triplet energy gap when compared to that of planar heptazethrene. Cethrene undergoes an intramolecular cyclization within several hours at room temperature.
