Au nanoparticle scaffolds modulating intermolecular interactions among the conjugated azobenzenes chemisorbed on curved surfaces: tuning the kinetics of cis-trans isomerisation

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Au nanoparticle scaffolds modulating intermolecular interactions among the conjugated azobenzenes chemisorbed on curved surfaces: tuning the kinetics of cis-trans isomerisation

JournalArticle (Originalarbeit in einer wissenschaftlichen Zeitschrift)

ID	3378935
Author(s)	Raimondo, Corinna; Kenens, Bart; Reinders, Federica; Mayor, Marcel; Uji-i, Hiroshi; Samori, Paolo
Author(s) at UniBasel	Mayor, Marcel
Year	2015
Title	Au nanoparticle scaffolds modulating intermolecular interactions among the conjugated azobenzenes chemisorbed on curved surfaces: tuning the kinetics of cis-trans isomerisation
Journal	Nanoscale
Volume	7
Number	33
Pages / Article-Number	13836-9
Abstract	Pi-pi intermolecular interactions among adjacent conjugated azobenzenes chemisorbed on (non-)flat Au surfaces can be tuned by varying the curvature of the Au nanoparticles. Here we show that such interactions rule the thermal cis-trans isomerization kinetics, towards a better control on the azobenzene bistability for its optimal integration as a responsive material.
Publisher	Royal Society of Chemistry
ISSN/ISBN	2040-3364
edoc-URL	http://edoc.unibas.ch/40740/
Full Text on edoc	Available
Digital Object Identifier DOI	10.1039/C5NR03688G
PubMed ID	http://www.ncbi.nlm.nih.gov/pubmed/26234482
ISI-Number	WOS:000359546900005
Document type (ISI)	Journal Article

19/04/2024

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