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A matter of greasy tails : interdigitation of alkyl chains in free and coordinated 4′-(4-dodecyloxyphenyl)-4,2′:6′,4″-terpyridines
JournalArticle (Originalarbeit in einer wissenschaftlichen Zeitschrift)
 
ID 1473617
Author(s) Constable, Edwin C.; Zhang, Guoqi; Housecroft, Catherine E.; Zampese, Jennifer A.
Author(s) at UniBasel Constable, Edwin Charles
Housecroft, Catherine
Year 2012
Title A matter of greasy tails : interdigitation of alkyl chains in free and coordinated 4′-(4-dodecyloxyphenyl)-4,2′:6′,4″-terpyridines
Journal Inorganic Chemistry Communications
Volume 15
Pages / Article-Number 113-116
Keywords Zinc, 4,2 ':6 ',4 ''-terpyridine, Crystal structure, Hydrophobic tail
Abstract The syntheses and single crystal structures of 4`-(4-dodecyloxyphenyl)-4,2`:6`,4 ``-terpyridine. 2, and [Zn-2(mu-OAc)(4)(2)(2)] are reported. Crystal packing is dominated by van der Waals interactions between fully extended alkyl chains producing lamellar structures in both compounds, and appears to be the reason for the formation of crystalline [Zn-2(mu-OAc)(4)(2)(2)] rather than a one-dimensional coordination polymer as observed for related compounds.
Publisher Elsevier
ISSN/ISBN 1387-7003
edoc-URL http://edoc.unibas.ch/dok/A6056196
Full Text on edoc No
Digital Object Identifier DOI 10.1016/j.inoche.2011.10.004
ISI-Number 000300812100028
Document type (ISI) Article
 
   

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