Artificial metalloenzymes as selective catalysts in aqueous media
JournalArticle (Originalarbeit in einer wissenschaftlichen Zeitschrift)
ID 116763
Author(s) Steinreiber, Johannes; Ward, Thomas R.
Author(s) at UniBasel Ward, Thomas R.
Year 2008
Title Artificial metalloenzymes as selective catalysts in aqueous media
Journal Coordination Chemistry Reviews
Volume 252
Number 5-7
Pages / Article-Number 751-766
Keywords asymmetric catalysis, artificial metalloenzymes, hybrid catalysts, designed evolution, redox reactions, hydrolysis, C-C bond formation, DNA-cleavage
Abstract The fusion of homogeneous and enzymatic catalysis has recently drawn attention due to reported novel activities and high selectivities. The incorporation of metal-catalysts into proteins combines the advantages of both catalytic strategies. Herein we summarize recent approaches of artificial metalloenzymes applied to catalysis. The discussion includes different strategies of anchoring and screening for improved selectivity.
Publisher Elsevier
ISSN/ISBN 0010-8545
Full Text on edoc No
Digital Object Identifier DOI 10.1016/j.ccr.2007.09.016
ISI-Number WOS:000254820800017
Document type (ISI) Review

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