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A versatile rhodium catalyst for acetalization reactions under mild conditions
Journal
Tetrahedron Letters
Volume
30
Number
45
Pages / Article-Number
6151-6154
Keywords
Carbonyl compounds Role: RCT (Reactant), RACT (Reactant or reagent) (acetalization of, under mild conditions in presence of rhodium complex catalysts); Acetalization catalysts (rhodium complexes, for carbonyl compds. under mild conditions); carbonyl compd acetalization rhodium catalyst
Abstract
Carbonyl compds. are readily acetalized under mild conditions in the presence of catalytic amts. of Rh(III)-MeC(CH2PPh2)3 complexes. Thus cyclohexanone reacted with HOCH2CH2OH to give 84% acetal I.
