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A review. Artificial metalloenzymes, based on the incorporation of a biotinylated catalytically active organometallic moiety within streptavidin, offer an attractive alternative to homogeneous, heterogeneous and enzymic catalysis. In this account, we outline our recent results and implications in the developments of such artificial metalloenzymes for various asym. transformations, including hydrogenation, transfer hydrogenation, allylic alkylation and sulfoxidn. [on SciFinder(R)]